The electrochemical modification of organic substrates bound to solid support
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The electrochemical modification of organic substrates bound to solid support

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Published in 2002 .
Written in English

Book details:

Edition Notes

ContributionsUniversity of Toronto. Dept. of Chemistry.
The Physical Object
Paginationvii, 61 leaves :
Number of Pages61
ID Numbers
Open LibraryOL19523141M

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  Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its   Electrochemical measurements were carried out using an Autolab PGSTAT10 electrochemical analysis system running GPE management software from Eco Chemie. The two electrode system was constructed as a thin layer cell configuration with a 4 mm 2 square gold sheet working electrode opposite to a solid state Ag/AgCl counter/reference. An Ag/AgCl ink   Electrochemical reduction of aryldiazonium salts (in acetonitrile or acidic aqueous medium) on an iron or mild steel surface permits the strong bonding (which resists an ultrasonic cleaning) of aryl groups on these surfaces. Attachment of aryl groups was demonstrated by the combined used of electrochemistry, infrared spectroscopy and polarization modulation infrared reflection spectroscopy The New Frontiers of Organic and Composite Nanotechnology is an attempt to illustrate current status of modern nanotechnology. The book is divided into 3 main sections, introduction and conclusion. The introduction describes general questions of the problem and main lines of the research ://

Two examples of selective electrochemical modification of individual nanoscale objects are presented, namely the electroless metallization of a plant virus, and the coupling of substituted phenyl Transformations of achiral organic substrates into chiral products by electrochemical synthetic methods require the active participation of an external source of chirality. Organic chemists working in this area have established a number of asymmetric electrochemical :// Electrochemical measurements evidence that the reaction results in a robust modification of Si() surfaces. XPS shows that organic films are monolayer thick and that covalent ≡SiAr bonding   The modified nanoparticles behave differently within organic solvents or polymer matrices compared to unmodified nanoparticles, e.g., the modified nanoparticles show comparatively better dispersion in both media. Download: Download full-size image; Fig. 1. Modification of a nanoparticle with 3-methacryloxypropyl ://

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